| Year ↓ | Round | Score | Opponent | Date / Time | City | Coach |
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| 2010 | First Round | 0-2 |  Argentina | Tue June 22, 2010 — 20:30 | Polokwane | Otto Rehhagel | | 2-1 |  Nigeria | Thu June 17, 2010 — 16:00 | Bloemfontein | | 0-2 |  South Korea | Sat June 12, 2010 — 13:30 | Port Elizabeth | | Qualifying Round Two | 1-0 |  Ukraine | Wed Nov 18, 2009 | Donetsk | | 0-0 | Sat Nov 14, 2009 | Athens | | Qualifying Round One | 2-1 |  Luxembourg | Wed Oct 14, 2009 | Athens | | 5-2 |  Latvia | Sat Oct 10, 2009 | Athens | | 1-1 |  Moldova | Wed Sep 9, 2009 | Chişinău | | 0-2 |  Switzerland | Sat Sep 5, 2009 | Basel | | 2-1 |  Israel | Wed Apr 1, 2009 | Heraklion | | 1-1 | Sat Mar 28, 2009 | Ramat-Gan | | 1-2 | Switzerland | Wed Oct 15, 2008 | Piraeus | | 3-0 | Moldova | Sat Oct 11, 2008 | Piraeus | | 2-0 | Latvia | Wed Sep 10, 2008 | Riga | | 3-0 | Luxembourg | Sat Sep 6, 2008 | Luxembourg | | | | | | | |
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| 2006 | Qualifying Round One | 1-0 |  Georgia | Wed Oct 12, 2005 | Piraeus | Otto Rehhagel | | 0-1 |  Denmark | Sat Oct 8, 2005 | København | | 2-1 |  Kazahkstan | Wed Sep 7, 2005 | Almaty | | 0-1 | Ukraine | Wed June 8, 2005 | Piraeus | | 0-0 |  Turkey | Sat June 4, 2005 | Istanbul | | 2-0 |  Albania | Wed Mar 30, 2005 | Piraeus | | 3-1 | Georgia | Sat Mar 26, 2005 | Tbilisi | | 2-1 | Denmark | Wed Feb 9, 2005 | Piraeus | | 3-1 | Kazahkstan | Wed Nov 17, 2004 | Piraeus | | 1-1 | Ukraine | Sat Oct 9, 2004 | Kyiv | | 0-0 | Turkey | Wed Sep 8, 2004 | Piraeus | | 1-2 | Albania | Sat Sep 4, 2004 | Tiranë | | | | | | | |
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| 2002 | Qualifying Round One | 2-2 |  England | Sat Oct 6, 2001 | Manchester | Otto Rehhagel | | Qualifying Round One | 1-5 |  Finland | Wed Sep 5, 2001 | Helsinki | Daniel Vassilis | | 0-2 | England | Wed June 6, 2001 | Athinai | | 1-0 | Albania | Sat June 2, 2001 | Iraklion | | 2-4 |  Germany | Wed Mar 28, 2001 | Athinai | | 0-2 | Albania | Wed Oct 11, 2000 | Tiranë | | 1-0 | Finland | Sat Oct 7, 2000 | Athinai | | 0-2 | Germany | Sat Sep 2, 2000 | Hamburg | | | | | | | |
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| 1998 | Qualifying Round One | 0-0 | Denmark | Sat Oct 11, 1997 | Athinai | Kostas Polychroniou | | 3-0 |  Slovenia | Sat Sep 6, 1997 | Ljubljana | | 0-1 |  Croatia | Wed Apr 30, 1997 | Thessaloniki | | 1-0 |  Bosnia-Herzegovina | Wed Apr 2, 1997 | Sarajevo | | 1-1 | Croatia | Sun Nov 10, 1996 | Zagreb | | 1-2 | Denmark | Wed Oct 9, 1996 | København | | 3-0 | Bosnia-Herzegovina | Sun Sep 1, 1996 | Kalamata | | 2-0 | Slovenia | Wed Apr 24, 1996 | Athinai | | | | | | | |
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| 1994 | First Round | 0-2 | Nigeria | Thu June 30, 1994 — 18:35 | Boston | Alketas Panagoulias | | 0-4 |  Bulgaria | Sun June 26, 1994 — 11:35 | Chicago | | 0-4 | Argentina | Tue June 21, 1994 — 12:05 | Boston | | Qualifying Round | 1-0 |  Russia | Wed Nov 17, 1993 | Athinai | | 3-1 | Luxembourg | Tue Oct 12, 1993 | Luxembourg |
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